Manolo Santana Stadium – Ora italiana: 11:00 (ora locale: 11:00 am)
1. Lucia Bronzetti vs [4] Elena Rybakina
2. Magda Linette vs [2] Aryna Sabalenka
3. Alexander Shevchenko vs [2] Carlos Alcaraz (non prima ore: 16:00)
4. Borna Coric vs [4] Alexander Zverev (non prima ore: 20:00)
5. [13] Danielle Collins vs [Q] Olga Danilovic
Arantxa Sanchez Stadium – Ora italiana: 11:00 (ora locale: 11:00 am)
1. [7] Andrey Rublev vs [Q] Facundo Bagnis
2. [WC] Juncheng Shang vs [27] Alejandro Davidovich Fokina
3. [6] Qinwen Zheng vs Yulia Putintseva (non prima ore: 15:00)
4. [7] Marketa Vondrousova vs Shelby Rogers
5. Mariano Navone vs [11] Holger Rune
Stadium 3 – Ora italiana: 11:00 (ora locale: 11:00 am)
1. [20] Anastasia Pavlyuchenkova vs [LL] Daria Saville
2. Cristina Bucsa vs [10] Daria Kasatkina
3. [8] Hubert Hurkacz vs Jack Draper
4. Luciano Darderi vs [12] Taylor Fritz
5. Jaume Munar vs [23] Jan-Lennard Struff
Court 4 – Ora italiana: 11:00 (ora locale: 11:00 am)
1. [15] Tommy Paul vs [Q] Lukas Klein
2. [26] Tomas Martin Etcheverry vs [PR] Denis Shapovalov
3. [Q] Jaqueline Cristian vs [22] Barbora Krejcikova
4. [26] Katie Boulter vs [WC] Robin Montgomery
5. [24] Tallon Griekspoor vs Taro Daniel
Court 5 – Ora italiana: 11:00 (ora locale: 11:00 am)
1. [21] Caroline Garcia vs Xinyu Wang
2. [WC] Victoria Jimenez Kasintseva vs [12] Jasmine Paolini
3. Hao-Ching Chan / Veronika Kudermetova vs Hanyu Guo / Xinyu Jiang
4. [8] Cristina Bucsa / Sara Sorribes Tormo vs Ingrid Gamarra Martins / Beatriz Haddad Maia (non prima ore: After Suitable Rest)
5. [OSE] Anhelina Kalinina / Dayana Yastremska vs Heather Watson / Yifan Xu (non prima ore: After Suitable Rest)
Court 6 – Ora italiana: 11:00 (ora locale: 11:00 am)
1. Fabian Marozsan vs [21] Francisco Cerundolo
2. Daniel Altmaier vs [31] Arthur Fils
3. [18] Sebastian Baez vs Luca Van Assche
4. [13] Ugo Humbert vs Botic van de Zandschulp
Court 7 – Ora italiana: 11:00 (ora locale: 11:00 am)
1. [28] Lorenzo Musetti vs Thiago Seyboth Wild
2. [14] Ekaterina Alexandrova vs Ashlyn Krueger
3. [25] Marta Kostyuk vs Mayar Sherif
4. Leylah Fernandez / Arantxa Rus vs [5] Lyudmyla Kichenok / Jelena Ostapenko
Court 8 – Ora italiana: 11:00 (ora locale: 11:00 am)
1. Mirra Andreeva vs [29] Linda Noskova
2. Caroline Dolehide vs [30] Anhelina Kalinina
3. [Q] Sara Bejlek vs [24] Anna Kalinskaya
4. [OSE] Lucia Bronzetti / Liudmila Samsonova vs Shuko Aoyama / Timea Babos (non prima ore: After Suitable Rest)
5. [4/WC] Coco Gauff / Taylor Townsend vs Anna Bondar / Tereza Mihalikova