STADIUM 1 – Ora italiana: 20:00 (ora locale: 11:00 am)
1. [WC] Andy Murray vs [Q] Taro Daniel
2. [11] Emma Raducanu vs Caroline Garcia (non prima ore: 22:00)
3. Alison Riske vs [8] Garbiñe Muguruza
4. [WC] Claire Liu vs [16] Cori Gauff (non prima ore: 03:00)
5. Adrian Mannarino vs Brandon Nakashima
STADIUM 2 – Ora italiana: 20:00 (ora locale: 11:00 am)
1. [3] Iga Swiatek vs Anhelina Kalinina
2. [1] Nikola Mektic / Mate Pavic vs [WC] John Isner / Jack Sock
3. [Q] Mikhail Kukushkin vs Tommy Paul
4. Ivan Dodig / Marcelo Melo vs [WC] Thanasi Kokkinakis / Nick Kyrgios (non prima ore: 03:00)
5. [25] Madison Keys vs Misaki Doi (non prima ore: 05:00)
STADIUM 3 – Ora italiana: 20:00 (ora locale: 11:00 am)
1. [24] Simona Halep vs Ekaterina Alexandrova
2. Dominik Koepfer vs Benoit Paire
3. [7] Wesley Koolhof / Neal Skupski vs Simone Bolelli / Fabio Fognini
4. [WC] Steve Johnson vs Daniel Altmaier (non prima ore: 02:00)
5. Tallon Griekspoor vs [WC] Sam Querrey
STADIUM 4 – Ora italiana: 20:00 (ora locale: 11:00 am)
1. Danka Kovinic vs [7] Karolina Pliskova
2. Raven Klaasen / Ben McLachlan vs [WC] Feliciano Lopez / Stefanos Tsitsipas
3. [12] Elina Svitolina vs [Q] Harriet Dart (non prima ore: 00:00)
4. Kaia Kanepi vs [22] Belinda Bencic (non prima ore: 02:00)
5. Qinwen Zheng vs [15] Angelique Kerber
STADIUM 5 – Ora italiana: 20:00 (ora locale: 11:00 am)
1. Richard Gasquet vs Oscar Otte
2. Jordan Thompson vs David Goffin
3. Ugo Humbert vs [Q] Holger Rune
4. Facundo Bagnis vs Henri Laaksonen
5. [Q] Tennys Sandgren vs Botic van de Zandschulp
STADIUM 6 – Ora italiana: 20:00 (ora locale: 11:00 am)
1. Aslan Karatsev / Andrey Rublev vs Roberto Bautista Agut / Alejandro Davidovich Fokina
2. Andrey Golubev / Alexander Zverev vs Daniel Evans / Karen Khachanov
3. [8] Caroline Dolehide / Storm Sanders vs Lyudmyla Kichenok / Jelena Ostapenko
4. [OSE] Maria Sakkari / Ajla Tomljanovic vs Petra Martic / Shelby Rogers (non prima ore: After Suitable Rest)
5. [WC] Dayana Yastremska / Ivanna Yastremska vs Irina-Camelia Begu / Monica Niculescu
STADIUM 7 – Ora italiana: 20:00 (ora locale: 11:00 am)
1. [Q] Philipp Kohlschreiber vs Emil Ruusuvuori
2. [Q] Jaume Munar vs [Q] Juncheng Shang
3. [Q] Liam Broady vs Miomir Kecmanovic
4. Ilya Ivashka vs Jan-Lennard Struff
5. Kamil Majchrzak vs [PR] Aljaz Bedene
STADIUM 8 – Ora italiana: 20:00 (ora locale: 11:00 am)
1. Petra Martic vs [19] Tamara Zidansek
2. Beatriz Haddad Maia vs [29] Clara Tauson
3. [33] Alizé Cornet vs [LL] Anna Kalinskaya
4. Ariel Behar / Gonzalo Escobar vs Federico Delbonis / Cameron Norrie
5. Ulrikke Eikeri / Erin Routliffe vs Marie Bouzkova / Lucie Hradecka
STADIUM 9 – Ora italiana: 20:00 (ora locale: 11:00 am)
1. Ajla Tomljanovic vs [26] Sorana Cirstea
2. [28] Liudmila Samsonova vs Ann Li
3. [23] Daria Kasatkina vs [WC] Katie Volynets
4. [OSE] Katerina Siniakova / Clara Tauson vs [7] Asia Muhammad / Ena Shibahara (non prima ore: After Suitable Rest)
5. [6] Desirae Krawczyk / Demi Schuurs vs Alexa Guarachi / Sabrina Santamaria